Issue 20

A. Borruto et alii, Frattura ed Integrità Strutturale, 20 (2012) 22-31; DOI: 10.3221/IGF-ESIS.20.03 26 The top section of sample 1 (Fig. 7) was examined to investigate the region under the pit (Fig. 8). This region shows the presence of infiltrations that provoke new pits. Figure 8 : Micrographic analysis. Under site of large pit surface. Presence of infiltration that give birth to new pits. – 200 X. Figure 9 : Micrographic analysis. Under site of scale surface. Discontinuous scale due to pronounced penetration. – 200 X. The side section of sample 2 (Fig. 7) was examined to investigate the region under the scale (Fig. 9). This region shows a deep intergranular penetration. In fact the surface scale appears very discontinuous. Electronic microscopy (SEM) and EDS analysis The electronic microscopic analysis (SEM) was carried out. Again the pit and the scales were examined. For each of the two samples previously taken, both sections already observed to MO and sides corresponding to the inner surface of the pipe were examined (Fig. 7). Pit The surface of the pit valley was examined (Fig. 7 – sample 1 surface). Fig. 10 and its magnification, Fig. 11, show the surface of the pit valley, badly damaged and the porous and sponge-like scale, no longer protective. EDS analysis was carried out on this surface, and it showed the presence of chromium and sulphur, all elements related to corrosive products such as iron and chromium oxides (Fig. 12, Tab. 1). Figure 10 : SEM analysis. Surface of the pit valley – 200 X. Figure 11 : SEM analysis. Magnification of a detail from fig. 10. – 1000 X. Figure 12 : SEM analysis. Pit surface. – 60 X.